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Amick's Rangers
Nitre District #4
Virginia was the leading niter producer during the Civil War with an estimated total production of about 500,000 pounds. Greenbrier has 105 caves, of Virginia's, found before 1812 and saltpeter was mined on a small-scale at over 100 caves in western Virginia. Because saltpeter production was widely scattered at many caves, it never was the principal target of Union attacks and many were still being mined at the end of the war.

Although organization of nitre works began in May 1861, and production was underway by August 1861, the Confederate Government didn't create the Nitre Districts until April 1862.  By then, much territory was lost to the yankees, a new state was forming, and yankee raids were frequent into Greenbrier County.
Journal of the Congress of the Confederate States of America, 1861-1865 [Volume 2]
FRIDAY, April 11, 1862. OPEN SESSION.
The President pro tempore having signed the following enrolled bills and enrolled joint resolution, they were delivered to the Secretary of the Senate, and by him forthwith presented to the President of the Confederate States for his approbation:
H. R. --
A bill for the organization of a corps of officers for the working of niter caves and establishing niter beds
Nitre District No. 4, Confederate Nitre and Mining Bureau, of Captain James Bradford Noyes, Greenbrier, Monroe, Pendleton and some adjoining counties in Virginia.

Greenbrier Organ Cave: Organ Cave is on the Midland Trail, the Old Saltpetre Route, a highway of nitre depots that supplied the government. Thomas Jefferson recorded that at least fifty nitre caves rested along the Greenbrier River. Confederate soldiers working under the direction of General Robert E. Lee found that Organ Cave was a suitable facility to extract nitre suitable for the powder mills of Augusta, Georgia. More than five miles of caverns and passages have been explored, but they are readily accessilbe for only a mile. Three-quarters of a mile from the entrance is the white stalactite formation for which the cave was named. The glistening columns resemble organ pipes in appearance and, when struck, produce notes of varying pitch. During the War between the States the cave was known as 'General Lee's Underground Powder Works'; 37 hoppers used at that time remain in one room of the cave  (http://www.organcave.com)

Greenbrier Anthony Creek: Anthony Creek passes through Gunpowder Ridge with numerous saltpeter caves.

Monroe, Saltpeter Caves: Greenville, Saltpeter was mined for the manufacture of gunpowder here.

Pendleton:
The caves have been known since the settlement of Pendleton County, in private ownership before July 19, 1787, when they were surveyed for John Penninger, and already being worked for saltpeter. The first operator was John Mefford who leased a property in 1795.  The caves were worked for saltpeter from then until the end of the Civil War. 1810 production of saltpeter was 4,000 pounds.  During the War of 1812, 12,500 pounds of gunpowder was manufactured on the site.  During the Civil War, the caves were operated for  the Confederacy and were frequently raided by Union troops.  In 1867, the property changed hands, passing from the McCoy family to the Hiner family.   (John the Miller Amick Powder Mill- circa 1810-20)
The Virginia Legislature created the Virginia State Line on May 15, 1862. The Virginia State Line was for men not liable for service under the Draft. The purpose of the State Line was to recover the western part of the State from Federal control. And  to protect the salt, lead, and saltpetre mines in Southwest Virginia, and guard the Virginia Tennessee Railroad. The Virginia State Line was answerable to the Adjutant General of the Commonwealth and the Governor of the Old Dominion, not Confederate officials.  The Virginia General Assembly abolished the Virginia State Line on March 31, 1863.  Several new commands were recruited from the disbanded men. Key among them were most of the 19th and 21st Virginia Cavalry Regiments. Virginia State Line flocked to the banner of James Milton French and his proposed 65th Virginia Infantry Regiment. The Virginia Legislature wanted to transfer these men to the Confederate Army as complete units. General Floyd however, furloughed his men February 28, 1863.  French's regiment was tentatively called the 65th Virginia Infantry and was composed of the remnants of the 4th and 5th Virginia State Line in recruited in Wise County

23rd Battalion Virginia Infantry   The formation of the 23rd was very different from many of the other units and became a complex unit to record. They were born out of the reorganization of the Confederate army in the spring of 1862. It was formed under Major David Stuart Hounshell in January 15, 1861, but it was a paper unit he never took command. The core was from Smyth County and physically uniting 1862 (a full five months after the order was given in Richmond in January). It was also known as: the First Battalion, Hounshell's Battalion and Derricks Battalion.
"I could hardly eat for a week till I got  ia and made tea an washed  mouth an not it is a getting better little Jace has bin sick ever since last Sunday last Sunday he never eat a bite all day but he is right smart better. I have not much to right: here I will in from you that the great Sapowers is at home he come on 10 days furlow he starts back to morrow. All the exempts has bin sent on to war. Andy hilten an frank grub is going to start to tasewal to day to dig salt petre rather than go to the army. An bill good has run off I no not whare to keep from going: I heard that day I got your letter that you all had gone to richmond an I was glad to hear from you: I want to no if you rote to alf to right to me and mon"  Thomas W. Fisher, 51 Va Inf
Process: The Confederate government utilized abundant cave deposits to create a steady supply of niter production, which involved extraction of the "peter dirt," leaching with water, and treatment with potassium salts obtained typically from wood ashes. Saltpeter is potassium nitrate that forms through nitrogen fixed by bacteria and transported in groundwater of cave sediments.  (NH3> -NO2> -NO3> KaNO3)

Saltpeter was extracted from the cave's dirt by using lye water. Water was poured through wood ashes and collected. Then the dirt was shoveled into the hoppers and the warm lye water was slowly mixed with the dirt. The lye water leached out the saltpeter and, when the water was boiled off, the saltpeter remained. 

Hoppers are large vats that held the nitrate rich soil mined by the soldiers. Each hopper was filled with over 2 tons of mined rock and soil, water poured over the soil leaching the minerals from the dirt, and colected into troughs placed beneath the hoppers. This water was then evaporated to leave behind saltpeter suitable for gunpowder.
Plate taken from 'Monuenta Pulveris Pyrll' depicting Berthold Schwarz, a semi-legendary German Franciscan monk of Freiburg, who real name was Konstantin Anklitzen, nicknamed Schwarz ('black') due to his chemical experiments. Around 1320 he is said to have brought gunpowder (or guns) into practical use.
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